EUR
en
Passat SL
Relevant identified uses : crop protection product, herbicide
According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (oral ) H302 Harmful if swallowed. Repr. 2 H361d Suspected of damaging the unborn child. Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. PMT EUH450 Can cause long -lasting and diffuse contamination of water resources vPvM EUH451 Can cause very long -lasting and diffuse contamination of water resources
According to Regulation (EC) No 1272/2008 [CLP] Globally Harmonized System, EU (GHS) Hazard Statement : H302 Harmful if swallowed. H361d Suspected of damaging the unborn child. H411 Toxic to aquatic life with long lasting effects. H400 Very toxic to aquatic life. EUH450 Can cause long -lasting and diffuse contamination of water resources EUH451 Can cause very long -lasting and diffuse contamination of water resources EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Precautionary Statement : P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read carefully and follow all instructions. Precautionary Statements (Prevention) : P280 Wear protective gloves, protective clothing and eye protection or face protection. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P270 Do not eat, drink or smoke when using this product. P264 Wash contaminated body parts thoroughly after handling. Precautionary Statements (Response) : P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P308 + P313 IF exposed or concerned: Get medical advice/attention. P391 Collect spillage. Precautionary Statem ents (Storage) : P405 Store locked up. Precautionary Statements (Disposal) : P501 Dispose of contents and container to hazardous or special waste collection point. Labeling of special preparations (GHS) : EUH208 : May produce an allergic reaction. Contains: 3-Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Hazard determining component(s) for labelling : 3-Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt , imazamox (ISO); ( RS) -2-(4 -isopropyl -4-methyl -5-oxo -2-imidazolin -2-yl) -5-methoxymethylnicotinic acid
According to Regulation (EC) No 1272/2008 [CLP] If applicable information is provided in this section on other hazards which do not result in classific ation but which may contribute to the overall hazards of the substance or mixture.
Chemical nature crop protection product, herbicide, Soluble concentrate (SL) Regulatory relevant ingredients 3-Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Content (W/W ): 43,81 % CAS Number : 50723 -80 -3 EC -Number : 256 -735 -4 Acute Tox. 4 (oral ) Eye Irrit. 2 Skin Sens. 1 Repr. 2 (unborn child ) Aquatic Acute 1 Aquatic Chronic 2 PMT vPvM H319, H302, H317, H361d, H411, H400, EUH450, EUH451 Acute toxicity estimate : oral : 1.600 mg/kg imazamox (ISO); (RS) -2-(4 -isopropyl -4-methyl -5-oxo -2-imidazolin -2-yl) -5-methoxymethylnicotinic acid Content (W/W ): 1,87 % CAS Number : 114311 -32 -9 Repr. 2 (unborn child ) Aquatic Acute 1 Aquatic Chronic 1 PMT M-factor acute : 10 M-factor chronic : 10 H361d, H400, H410, EUH450
Remove contaminated clothing. If inhaled : Keep patient calm, remove to fresh air, seek medical attention. On skin contact : Wash thoroughly with soap and water On contact with eyes : Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion : Immediately rinse mouth and then drink 200 -300 ml of water, seek medical attention.
Sy mptoms : Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11., (Further) symptoms and / or effects are not known so far Hazards : Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11. (Further) symptoms and / or effects are not kno wn so far
Treatment : Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Suitable extinguishing media : water spray, foam, dry powder, carbon dioxide
Endangering substances : Carbon monoxide , Carbon dioxide , hydrogen chloride , Hydrogen bromide , nitrogen oxides, sulfur oxides, halogenated compounds, silica compounds Advice : The substances/groups of substances mentioned can be released in case of fire.
Special protective equipment : Wear self -contained breathing ap paratus and chemical -protective clothing. Further information : Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire.
Do not breathe vapour/spray. Use personal protective clothing. Avoid contact with the skin, eyes and clothing.
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
For small amounts : Pick up with suitable absorbent material (e.g. sand, sawdust, general -purpose binder, kieselguhr). For large amounts : Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Protection against fire and explosion : No special precautions necessary. The substance/product is non -combustible. Product is not explosive.
Segregate from foods and animal feeds. Further information on storage conditions : Keep away from heat. Protect from direct sunlight. Storage stability : Storage duration : 60 Months Protect from temperatures below: -5 °C Changes in the properties of the product may occur if substance/product is stored below indicated temp erature for extended periods of time. Protect from temperatures above:40 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.
For the rele vant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.
Components with occupational exposure limits 50723 -80 -3: 3-Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt TWA value 1,23 mg/m3 (BASF recomm. occupational exposure limit )
Personal protective equipment Respiratory protection : Suitable respiratory protection for higher concentrations or long -term effect: Combination filter for gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK). Hand protection : Suitable chemical resistant safet y gloves (EN ISO 374 -1) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN ISO 374 -1): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc. Eye protection : Safety glasses with side -shields (frame goggles) (e.g. EN 166) Body protection : Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical -protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust). General safety and hygiene measures The stateme nts on personal protective equipment in the instructions for use apply when handling crop -protection agents in final -consumer packing. Wearing of closed work clothing is recommended. Store work clothing separately. Keep away from food, drink and animal fee ding stuffs.
State of matter : liquid Form : liquid Colour : red -brown Odour : odourless Odour threshold : not applicable, odour not perceivable Melting temperature : The product has not been tested. Boiling point : approx. 100 °C (1.013 hPa ) Information applies to the solvent. Flammability : not flammable Lower explosion limit : As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Upper explosion limit : As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Flash point : No flash point - Measurement made up to the boiling point. Auto -ignition temperature : approx. 546 °C (Directive 92/69/EEC, A.15 ) Thermal decomposition : 170 °C , 250 kJ/kg (DSC (OECD 113) ) (onset temperature) 300 °C , 70 kJ/kg (DSC (OECD 113) ) (onset temperature) Not a substance liable to self -decomposition according to UN transport regulations, class 4.1. SADT : > 75 °C Heat accumulation / Dewar 500 ml (SADT, UN -Test H.4, 28.4.4) pH value : approx. 5 - 7 (CIPAC standard water D , 1 %(m) , 21 °C ) Viscosity, kinematic : approx. 8,45 mm2/s (20 °C ) (calculated (from dynamic viscosity) ) Viscosity, dynamic : 9,377 mPa.s (20 °C , 200 1/s ) (OECD Guideline 114 ) Thixotropy : not thixotropic Solubility in water : soluble Partitioning coefficient n -octanol/water (log Kow) : The statements are based on the properties of the individual components. Information on: 3-Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Partitioning coefficient n -octanol/water (log Kow) : 0,67 (20 °C ; pH value : 5) Vapour pressure : approx. 23,4 hPa (20 °C ) Information applies to the solvent. Density : approx. 1,2 g/cm3 (20 °C ) Relative vapour density (air) : not determined Particle characteristics Particle size distribution : The substance / product is marketed or used in a non solid or granular form.
Information with regard to physical hazard classes Explosives Explosion hazard : not explosive Oxidizing properties Fire promoting properties : not fire -propagating (Directive 2004/73/EC, A.21 )
No hazardous reactions if stored and handled as prescribed/indicated.
The product is stable if stored and handled as prescribed/indicated.
No hazardous reactions if stored and handled as prescribed/indicated.
See SDS section 7 - Handling and storage.
Substances to avoid : strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products : No hazardous decomposition products if stored and handled as prescribed/indicated.
Acute toxicity Assessment of acute toxicity : Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Experimental/calculated data : LD50 rat (oral ): > 300 - < 2.000 mg/kg (OECD Guideline 423 ) LC50 rat (by inhalation ): > 5 mg/l 4 h (OECD Guideline 403 ) An aerosol was tested. LD50 rat (dermal ): > 2.000 mg/kg (OECD Guideline 402 ) No mortality was observed. Irritation Assessment of irritating effects : Not irritating to eyes and skin. Experimental/calculated data : Skin corrosion/irritation rabbit : non -irritant (OECD Guideline 404 ) Serious eye damage/irritation rabbit : non -irritant (OECD Guideline 405 ) Respiratory/Skin sensitization Assessment of sensitization : No sensitizing effect. Experimental/calculated data : Mouse Local Lymph Node Assay (LLNA) mouse : Non -sensitizing. (OECD Guideline 429 ) Germ cell mutagenicity Assessment of mutagenicity : The product has not been tested. The statement has been derived from the properties of the individual components. Mutagen icity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity : The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no i ndication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity : The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect. Developmental toxicity Assessment of teratogenicity : The product has not been tested. The statement has been derived from the properties of the individual components. Inf ormation on: 3-Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Assessment of teratogenicity : Indications of possible developmental toxicity/teratogenicity were seen in animal studies. The substance did not cause malformations in anim al studies. When given in high doses fetotoxicity was observed. Information on: imazamox (ISO); (RS) -2-(4 -isopropyl -4-methyl -5-oxo -2-imidazolin -2-yl) -5-methoxymethylnicotinic acid Assessment of teratogenicity : Indications of possible developmental toxic ity/teratogenicity were seen in animal studies. Specific target organ toxicity (single exposure) Assessment of STOT single : Based on the available i nformation there is no specific target organ toxicity to be expected after a single exposure. Remarks : The product has not been tested. The statement has been derived from the properties of the individual components. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity : The product has not been tested. The statement has been derived from the properties of the individual components. No substance -specific organtoxicity was observed after repea ted administration to animals. Aspiration hazard not applicable Interactive effects No data available.
Other information Other relevant toxicity information Misuse can be harmful to health.
Assessment of aquatic toxicity : Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Toxicity to fish : LC50 (96 h ) > 100 mg/l , Oncorhynchus mykiss (OECD 203; ISO 7346; 92/69/EWG, C.1 , static ) Aquatic invertebrates : LC50 (48 h ) > 100 mg/l , Daphnia magna (OECD Guideline 202, part 1 ) Aquatic plants : EC50 (72 h ) > 100 mg/l (growth rate ), Pseudokirchneriella subcapitata (OECD Guideline 201 ) The value meets the highest applied test concentration. No observed effect concentration (72 h ) 4,6 mg/l (growth rate ), Pseudokirchneriella subcapitata (OECD Guideline 201 ) EC50 (7 d ) 0,79 mg/l (growth rate ), Lemna gibba (OECD Guideline 221 ) EC10 (7 d ) 0,15 mg/l (growth rate ), Lemna gibba (OECD Guideline 221 )
Assessment biodegradation and elimination (H2O) : The product has not been tested. The statement has been derived from the properties of the individual components. Information on:3 -Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Assessment biodegradation and elimination (H2O) : Not r eadily biodegradable (by OECD criteria). Information on:imazamox (ISO); (RS) -2-(4 -isopropyl -4-methyl -5-oxo -2-imidazolin -2-yl) -5-methoxymethylnicotinic acid Assessment biodegradation and elimination (H2O) : Not readily biodegradable (by OECD criteria).
Assessment bioaccumulation potential : The product has not been tested. The statement has been derived from the properties of the individual components. Information on:3 -Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Bioaccumulation potential : Because of the n -octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Information on:imazamox ( ISO); (RS) -2-(4 -isopropyl -4-methyl -5-oxo -2-imidazolin -2-yl) -5-methoxymethylnicotinic acid Bioaccumulation potential : Bioconcentration factor (BCF ): < 1 , Lepomis macrochirus (OECD Guideline 305 ) Does not accumulate in organisms.
Assessment transport between environmental compartments : Adsorption in soil : The product has not been tested. The statement has been derived from the properties of the individual components. Information on:3 -Isopropyl -1H -2,1,3 -benzothiadiazin -4(3H) -one 2,2 -dioxide, sodium salt Assessment transport between environmental compartments : Adsorption in soil : Following exposure to soil, the product trickles away and can - dependant on degradation - be transported to deeper soil areas with larger water loads. Information on:imazamox (ISO); (RS) -2-(4 -isopropyl -4-methyl -5-oxo -2-imidazolin -2-yl) -5-methoxymethylnic otinic acid Assessment transport between environmental compartments : Volatility : The substance will not evaporate into the atmosphere from the water surface. Adsorption in soil : Following exposure to soil, the product trickles away and can - dependant o n degradation - be transported to deeper soil areas with larger water loads.
The product does not contain substances that are listed in Regulation (EU) 2024/590 on substances that deplete the ozone layer. Additional information Other ecotoxicological advice : Do not discharge product into the environment without control.
Must be sent to a suitable incineration plant, observing local regulations. Contaminated packaging : Contaminated packaging should be emptied as far as possible and disposed of in the same m anner as the substance/product.
To avoid risks to man and the environment, comply with the instructions for use.
Full text of the classifications, including the hazard classes and the hazard statements, if mentioned in section 2 or 3: Acute Tox. Acute toxicity Repr. Reproductive toxicity Aquatic Acute Hazardous to the aquatic environment - acute Aquatic Chronic Hazardous to the aquatic environment - chronic Persistent, Mobile and Toxic or Very Persistent, Very Mobile properties Eye Irrit. Eye irritation Skin Sens. Skin sensitization H302 Harmful if swallowed. H361d Suspected of damaging the unborn child. H411 Toxic to aquatic life with long lasting effects. H400 Very toxic to aquatic life. EUH450 Can cause long -lasting and diffuse contamination of water resources EUH451 Can cause very long -lasting and diffuse contamination of water resources EUH401 To avoid risks to human health and the environment, comply with the instructions for use. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. Abbreviations ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road. ADN = The European Agreement concerning the International Carriage of Dangerous Goods by Inland waterways. ATE = Acute Toxicity Estimates. CAO = Cargo Aircraft O nly. CAS = Chemical Abstract Service. CLP = Classification, Labelling and Packaging of substances and mixtures. DIN = German national organization for standardization. DNEL = Derived No Effect Level. EC50 = Effective concentration median for 50% of the po pulation. EC = European Community. EN = European Standards. IARC = International Agency for Research on Cancer. IATA = International Air Transport Association. IBC -Code = Intermediate Bulk Container code. IMDG = International Maritime Dangerous Goods Code . ISO = International Organization for Standardization. STEL = Short -Term Exposure Limit. LC50 = Lethal concentration median for 50% of the population. LD50 = Lethal dose median for 50% of the population. TLV = Threshold Limit Value. MARPOL = The Internati onal Convention for the Prevention of Pollution from Ships. NEN = Dutch Norm. NOEC = No Observed Effect Concentration. OEL = Occupational Exposure Limit. OECD = Organization for Economic Cooperation and Development. PBT = Persistent, Bioaccumulative and To xic. PMT = Persistent, Mobile and Toxic. PNEC = Predicted No Effect Level. PPM = Parts per million. RID = The European Agreement concerning the International Carriage of Dangerous Goods by Rail. TWA = Time Weight Average. UN -number = UN number at transport . vPvB = very Persistent and very Bioaccumulative. vPvM = very Persistent and very Mobile. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. Thi s safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual qu ality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed. Vertical lines in the left hand margin indicate an amendment from the previous version.
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