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EG-SDB

    Safety Data Sheet

    Vapouriz Nic Salts - MENTHOL SPECIAL BLEND 20MG (50/50)

    Section 1: Identification

    Vapouriz Nic Salts - MENTHOL SPECIAL BLEND 20MG (50/50)

    To use in electronic cigarettes.

    Section 2: Hazards identification

    Toxic if swallowed. Harmful to aquatic life with long lasting effects.

    3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO)

    Toxic if swallowed. Harmful to aquatic life with long lasting effects.

    Contains p-menthan-3-one, Isomenthone. May produce an allergic reaction.

    The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

    Section 3: Composition/information on ingredients

    3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO) 1 - < 5 % Acute Tox. 2, Acute Tox. 2, Acute Tox. 2, Aquatic Chronic 2; H330 H310 H300 H411 L-Menthol 1 - < 5 % Skin Irrit. 2, Eye Irrit. 2; H315 H319 p-menthan-3-one < 1 % Skin Irrit. 2, Skin Sens. 1B; H315 H317 Isomenthone < 1 % Skin Irrit. 2, Skin Sens. 1B; H315 H317

    Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article 59 (REACH)

    Section 4: First aid measures

    In case of accident or unwellness, seek medical advice immediately.

    In case of accident by inhalation: remove casualty to fresh air and keep at rest. In case of respiratory tract irritation, consult a physician.

    Gently wash with plenty of soap and water. In case of skin irritation, seek medical treatment. Change contaminated clothing.

    Rinse cautiously with water for several minutes. In case of troubles or persistent symptoms, consult an ophthalmologist.

    Rinse mouth thoroughly with water. Let water be drunken in little sips ( dilution effect). Do NOT induce vomiting. Call a physician immediately.

    Section 5: Firefighting measures

    Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.

    High power water jet.

    Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Nitrogen oxides (NOx). In case of fire: Wear self-contained breathing apparatus.

    Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Co-ordinate fire-fighting measures to the fire surroundings.

    Section 6: Accidental release measures

    Ventilate affected area. Avoid contact with skin, eyes and clothes. Wear personal protection equipment.

    Absorb with liquid-binding material. Treat the recovered material as prescribed in the section on waste disposal . Clean contaminated objects and areas thoroughly observing environmental regulations.

    Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13

    Section 7: Handling and storage

    Provide adequate ventilation as well as local exhaustion at critical locations. Wear suitable protective clothing.

    Usual measures for fire prevention.

    Keep container tightly closed in a cool, well-ventilated place. Make sure spills can be contained, e.g. in sump pallets or kerbed areas.

    Do not store together with: Explosives. Gas. Oxidizing liquids. Oxidizing solids. Self-reactive substances and mixtures. Organic peroxides. Ammonium nitrate. Combustible toxic substances. Non-combustible toxic substances. Radioactive substances. Infectious substances.

    Keep the packing dry and well sealed to prevent contamination and absorbtion of humidity. Recommended storage temperature: 15-25°C Protect against: Light. UV-radiation/sunlight. heat. moisture.

    See section 1.

    Section 8: Exposure controls/personal protection

    -Glycerol, mist 10 -Nicotine 54-11-5 0.5 1.5 Propane-1,2-diol, total vapour and particulates 57-55-6 150 474

    propane-1,2-diol Worker DNEL, long-term inhalation systemic 168 mg/m³ Worker DNEL, long-term inhalation local 10 mg/m³ Consumer DNEL, long-term dermal systemic 213 mg/kg bw/day Consumer DNEL, long-term inhalation systemic 50 mg/m³ Consumer DNEL, long-term oral systemic 85 mg/kg bw/day Consumer DNEL, long-term inhalation local 10 mg/m³

    propane-1,2-diol Freshwater 260 mg/l Freshwater (intermittent releases) 183 mg/l Marine water 26 mg/l Marine water (intermittent releases) 183 mg/l Freshwater sediment 572 mg/kg Marine sediment 57,2 mg/kg Micro-organisms in sewage treatment plants (STP) 20000 mg/l Soil 50 mg/kg

    If handled uncovered, arrangements with local exhaust ventilation should be used if possible.

    Always close containers tightly after the removal of product. When using do not eat, drink, smoke, sniff. Wash hands before breaks and after work. Take off contaminated clothing and wash it before reuse .

    Wear safety glasses; chemical goggles (if splashing is possible).

    Wear suitable gloves. Suitable material: FKM (fluororubber). - Thickness of glove material: 0,4 mm Breakthrough time >= 8 h Butyl rubber. - Thickness of glove material: 0,5 mm Breakthrough time >= 8 h CR (polychloroprenes, Chloroprene rubber). - Thickness of glove material: 0,5 mm Breakthrough time >= 8 h NBR (Nitrile rubber). - Thickness of glove material: 0,35 mm Breakthrough time >= 8 h PVC (Polyvinyl chloride). - Thickness of glove material: 0,5 mm Breakthrough time >= 8 h The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them before taking off and air them well.

    Suitable protective clothing: Lab apron. Minimum standard for preventive measures while handling with working materials are specified in the TRGS 500.

    With correct and proper use, and under normal conditions, breathing protection is not required. Respiratory protection necessary at: aerosol or mist formation exceeding exposure limit values insufficient ventilation Suitable respiratory protective equipment: Combination filtering device (EN 14387) Type A/P2-3 The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus must be used. Use only respiratory protection equipment with CE-symbol including four digit test number. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection apparatus (BGR 190).

    Do not allow uncontrolled discharge of product into the environment.

    Section 9: Physical and chemical properties

    characteristic

    not determined

    not determined

    Not sustaining combustion

    not determined

    none

    not determined

    not determined

    not determined

    none

    not determined

    not determined

    not determined

    not determined

    not determined

    not determined

    not determined

    not determined

    not determined

    Section 10: Stability and reactivity

    The product is chemically stable under recommended conditions of storage, use and temperature.

    Protect against: UV-radiation/sunlight. heat.

    Materials to avoid: Oxidizing agents, strong. Reducing agents, strong.

    Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Nitrogen oxides (NOx).

    Section 11: Toxicological information

    Toxic if swallowed. nicotine (ISO); 3-[(2S)-1-methylpyrrolidin-2-yl]pyridine: LD 50 oral = 5 mg/kg [3,34 - 24 mg]; Species: Mouse. LD 50 dermal = 70 mg/kg; Species: Rabbit . Method: OECD Guideline 402 LC 50 Inhalation = 0,19 mg/l; Species: Rat.

    ATE (oral) 181,6 mg/kg

    3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO) ATE 5 mg/kg oral ATE 70 mg/kg dermal inhalation aerosol ATE 0,19 mg/kg L-Menthol Rat LD50 >2000 mg/kg oral inhalation (4 h) aerosol LC50 5,289 mg/l Rat

    Based on available data, the classification criteria are not met. nicotine (ISO); 3-[(2S)-1-methylpyrrolidin-2-yl]pyridine: Irritant effect on the respiratory tract: slightly irritant but not relevant for classification. Irritant effect on the eye: Method: OECD Guideline 437 Species: in vitro; Result: negative. Irritant effect on the skin: slightly irritant but not relevant for classification.

    Contains p-menthan-3-one, Isomenthone. May produce an allergic reaction. nicotine (ISO); 3-[(2S)-1-methylpyrrolidin-2-yl]pyridine: Skin sensitisation: Method: OECD Guideline 429 Species: Mouse ;Result: negative.

    Based on available data, the classification criteria are not met. nicotine (ISO); 3-[(2S)-1-methylpyrrolidin-2-yl]pyridine: In-vitro mutagenicity: Ames test negative.

    Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. nicotine (ISO); 3-[(2S)-1-methylpyrrolidin-2-yl]pyridine: NOAEL: 1,25 mg/kg (EFSA, 2009)

    Based on available data, the classification criteria are not met. There are no data available on the mixture itself.

    Section 12: Ecological information

    3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO) 54-11-5 Acute fish toxicity 96 h LC50 4 mg/l Oncorhynchus mykiss Acute algae toxicity 72 h ErC50 37 mg/l Desmodesmus subspicatus Acute crustacea toxicity 48 h EC50 0,242 mg/l Daphnia magna L-Menthol 2216-51-5 Acute fish toxicity 96 h LC50 15,6 mg/l Brachydanio rerio (zebra-fish) Acute algae toxicity 72 h ErC50 20 mg/l Desmodesmus subspicatus Acute crustacea toxicity 48 h EC50 37,7 mg/l Daphnia magna

    3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO) 54-11-5 71% 28 Easily biodegradable L-Menthol 79% 28 Easily biodegradable

    3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO) 54-11-5 1,17 L-Menthol 2216-51-5 3,4

    The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

    Do not allow to enter into surface water or drains.

    Section 13: Disposal considerations

    Observe in addition any national regulations! Consult the local waste disposal expert about waste disposal. Non-contaminated packages may be recycled.

    160305 organic wastes containing hazardous substances; hazardous waste

    160305 organic wastes containing hazardous substances; hazardous waste

    150110 packaging containing residues of or contaminated by hazardous substances; hazardous waste Handle contaminated packages in the same way as the substance itself.

    Section 14: Transport information

    UN 3144 NICOTINE PREPARATION, LIQUID, N.O.S. (3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO))

    6.1

    III

    T1 43 274 5 L E1 260 E

    UN 3144

    NICOTINE PREPARATION, LIQUID, N.O.S. (3-(N-methyl-2-pyrrolidinyl)pyridine, nicotine (ISO))

    6.1

    III

    T1 43 274 5 L E1

    UN 3144 NICOTINE PREPARATION, LIQUID, N.O.S. (Nicotine (ISO))

    6.1

    III

    43, 223, 274 5 L E1 F-A, S-A

    UN 3144 NICOTINE PREPARATION, LIQUID, N.O.S. (Nicotine (ISO))

    6.1

    III

    A3 A4 A6 2 L Y642 E1 655 60 L 663 220 L

    Refer to section 6-8

    Section 15: Regulatory information

    The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP]. REACH 1907/2006 Appendix XVII, No (mixture): 3

    2 - clearly water contaminating

    For the following substances of this mixture a chemical safety assessment has been carried out: propane-1,2-diol

    Section 16: Other information

    H300 Fatal if swallowed. H301 Toxic if swallowed. H310 Fatal in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H330 Fatal if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH208 Contains p-menthan-3-one, Isomenthone. May produce an allergic reaction.

    Classification according EC regulation 1272/2008 (CLP): - Classification procedure: Health hazards: Calculation method. Environmental hazards: Calculation method. Physical hazards: On basis of test data. and / or calculated and / or estimated. The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

    (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)

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