EUR
en
1.1 Product identifier Trade name R-1605, R-2500, R-2504, R-2509, R-2513, K-2513 Ampoules, K-2523 Ampoules, K-2703 Ampoules, R-2705, R-5502, R-5808, R-7404, K-7423 Ampoules, R-7904, R-7904A, R-7904B, R-7904C, R-7904D, K-7913 Ampoules Other means of identification Chlorine, Chlorine Dioxide, Ozone and Peracetic Acid CHEMets® Refills & Vacu-vials® Ampoules, Peracetic Acid VACUettes Refills, Bromine, Hydro-gen Peroxide, Hypochlorite CHEMets® Refills 1.2 Relevant identified uses of the substance or mixture and uses advised against Component of water analysis test kits: I-2001, I-2005, I-2019, I-2020, K-1605, K-2500, K-2504, K-2504A, K-2504B, K-2504C, K-2504D, K-2513, K-2523, K-2703, K-2705, K-5502, K-5808, K-5816, K-7404, K-7423, K-7904, K-7904A, K-7904B, K-7904C, K-7904D, K-7913 1.3 Details of the supplier of the safety data sheet CHEMetrics, Inc. 4295 Catlett Road Midland VA 22728 United States Telephone: 1-540-788-9026 Telefax: 1-540-788-4856 e-mail: technical@chemetrics.com Website: www.chemetrics.com 1.4 Emergency telephone number Emergency information service ChemTel Inc.: 1-800-255-3924, +01-813-248-0585
2.1 Classification of the substance or mixture Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) Section Hazard class Category Hazard class and cat-egory Hazard state-ment 2.6 flammable liquid 4 Flam. Liq. 4 H227 3.4S skin sensitization 1 Skin Sens. 1 H317 2.2 Label elements Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word warning - Pictograms GHS07 - Hazard statements H227 Combustible liquid. H317 May cause an allergic skin reaction. - Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P302+P352 IF ON SKIN: Wash with plenty of water. P321 Specific treatment (see on this label). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish. P403 Store in a well-ventilated place. P501 Dispose of contents/container to industrial combustion plant.
3.1 Substances Not relevant (mixture) 3.2 Mixtures Description of the mixture Name of substance Identifier Wt% Classification acc. to GHS Pictograms water CAS No 7732-18-5 ≥ 94 acetone CAS No 67-64-1 ≤ 4 Eye Irrit. 2 / H319 STOT SE 3 / H336 Flam. Liq. 2 / H225 Potassium phosphate mono-basic CAS No 7778-77-0 1 Acute Tox. 3 / H331 CDTA CAS No 125572-95-4 13291-61-7 0.4 N,N-Diethyl-p-Phenylene-diamine Oxalic Acid Salt (DPD) CAS No 62637-92-7 0.1 Skin Sens. 1 / H317 Muta. 2 / H341 sodium hydroxide CAS No 1310-73-2 0.08 Skin Corr. 1A / H314 Eye Dam. 1 / H318
4.1 Description of first-aid measures General notes Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth. Following inhalation If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air. Following skin contact Wash with plenty of soap and water. Following eye contact Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Following ingestion Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed Symptoms and effects are not known to date.
5.1 Extinguishing media Suitable extinguishing media Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2) Unsuitable extinguishing media Water jet 5.2 Special hazards arising from the substance or mixture In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent vapors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Hazardous combustion products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2) 5.3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance.
6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Remove persons to safety. For emergency responders Wear breathing apparatus if exposed to vapors/dust/aerosols/gases. 6.2 Environmental precautions Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. 6.3 Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains Advice on how to clean up a spill Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder Appropriate containment techniques Use of adsorbent materials. Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area.
7.1 Precautions for safe handling Recommendations Wear impact- and splash-resistant eyewear. Break the ampoule tip only when it is completely im-mersed in sample. Breaking the tip in air may cause the glass ampoule to shatter. - Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharge. Use only in well-ventilated areas. Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. - Specific notes/details Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are par-ticularly prone to the presence of flammable substances or mixtures. Vapors are heavier than air, spread along floors and form explosive mixtures with air. Vapors may form explosive mixtures with air. Advice on general occupational hygiene Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equip-ment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in con-tainers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs. 7.2 Conditions for safe storage, including any incompatibilities Managing of associated risks - Explosive atmospheres Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool. Protect from sunlight. - Flammability hazards Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flames and other igni-tion sources. No smoking. Take precautionary measures against static discharge. Protect from sunlight. - Ventilation requirements Use local and general ventilation. Ground/bond container and receiving equipment. 7.3 Other information For optimum analytical performance, store in the dark and at room temperature.
8.1 Control parameters Occupational exposure limit values (Workplace Exposure Limits) Coun-try Name of agent CAS No Identi-fier TWA [ppm] TWA [mg/m³] STEL [ppm] STEL [mg/m³] Ceiling-C [ppm] Ceiling-C [mg/m³] Nota-tion Source US sodium hydroxide 1310-73-2 REL 2 NIOSH REL US sodium hydroxide 1310-73-2 TLV® 2 ACGIH® 2019 US sodium hydroxide 1310-73-2 PEL 2 29 CFR 1910.100 0US sodium hydroxide (caustic soda) 1310-73-2 PEL (CA) 2 Cal/ OSHA PEL US acetone 67-64-1 PEL (CA) 500 1,200 750 1,780 3,000 Cal/ OSHA PEL US acetone 67-64-1 REL 250 (10 h) 590 (10 h) NIOSH REL US acetone 67-64-1 TLV® 250 500 ACGIH® 2019 US acetone 67-64-1 PEL 1,000 2,400 29 CFR 1910.100 0Notation Ceiling-C ceiling value is a limit value above which exposure should not occur STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period (unless otherwise specified) TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted average (unless otherwise specified Biological limit values Country Name of agent Parameter Notation Identifier Value Source US acetone acetone BEI® 25 mg/l ACGIH® 2019 Relevant DNELs of components of the mixture Name of substance CAS No Endpoint Threshold level Protection goal, route of exposure Used in Exposure time acetone 67-64-1 DNEL 1,210 mg/m³ human, inhalatory worker (industry) chronic - systemic ef-fects acetone 67-64-1 DNEL 2,420 mg/m³ human, inhalatory worker (industry) acute - local effects Relevant DNELs of components of the mixture Name of substance CAS No Endpoint Threshold level Protection goal, route of exposure Used in Exposure time acetone 67-64-1 DNEL 186 mg/kg bw/day human, dermal worker (industry) chronic - systemic ef-fects Potassium phosphate monobasic 7778-77-0 DNEL 14.82 mg/m³ human, inhalatory worker (industry) chronic - systemic ef-fects sodium hydroxide 1310-73-2 DNEL 1 mg/m³ human, inhalatory worker (industry) chronic - local effects Relevant PNECs of components of the mixture Name of substance CAS No Endpoint Threshold level Organism Environmental compartment Exposure time acetone 67-64-1 PNEC 10.6 mg /l aquatic organisms freshwater short-term (single in-stance) acetone 67-64-1 PNEC 1.06 mg /l aquatic organisms marine water short-term (single in-stance) acetone 67-64-1 PNEC 100 mg /l aquatic organisms sewage treatment plant (STP) short-term (single in-stance) acetone 67-64-1 PNEC 30.4 mg /kg aquatic organisms freshwater sediment short-term (single in-stance) acetone 67-64-1 PNEC 3.04 mg /kg aquatic organisms marine sediment short-term (single in-stance) acetone 67-64-1 PNEC 29.5 mg /kg terrestrial organ-isms soil short-term (single in-stance) CDTA 125572-95-4 13291-61-7 PNEC 2.77 μg /l aquatic organisms freshwater short-term (single in-stance) CDTA 125572-95-4 13291-61-7 PNEC 0.277 μg /l aquatic organisms marine water short-term (single in-stance) CDTA 125572-95-4 13291-61-7 PNEC 19 mg /l aquatic organisms sewage treatment plant (STP) short-term (single in-stance) CDTA 125572-95-4 13291-61-7 PNEC 2.17 μg /kg aquatic organisms freshwater sediment short-term (single in-stance) CDTA 125572-95-4 13291-61-7 PNEC 0.217 μg /kg aquatic organisms marine sediment short-term (single in-stance) CDTA 125572-95-4 13291-61-7 PNEC 0.327 μg /kg terrestrial organ-isms soil short-term (single in-stance) 8.2 Exposure controls Appropriate engineering controls General ventilation. Individual protection measures (personal protective equipment) Eye/face protection Wear eye/face protection. Skin protection - Hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tight-ness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves men-tioned above together with the supplier of these gloves. - Other protection measures Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thoroughly after handling. Respiratory protection In case of inadequate ventilation wear respiratory protection. Environmental exposure controls Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
9.1 Information on basic physical and chemical properties Product description CHEMets Refills: Sealed glass ampoules, 7 mm OD, for visual colorimetric water analysis. Each CHEMet™ ampoule contains approximately 0.2 - 0.5 mL of liquid reagent sealed under vacuum. Refills contain 30 am-poules, test kits contain 1 refill. VACUettes Refills: Sealed glass ampoules, 7 mm OD, with small glass capillary attached, for visual colorimetric water ana-lysis. Each VACUette™ ampoule contains approximately 0.2 - 0.5 mL of liquid reagent sealed under vacuum. Refills contain 30 ampoules, test kits contain 1 refill. Vacu-vials Ampoules: Sealed glass ampoules, 13 mm OD, for instrumental colorimetric water analysis. Each Vacu-vial™ am-poule contains approximately 0.8 - 2 mL of liquid reagent sealed under vacuum. Test kits contain 30 ampoules. Appearance Physical state liquid Color colorless to pale pink Odor odorless Other safety parameters pH (value) 6.3 Melting point/freezing point -7 °C Initial boiling point and boiling range 94 °C Flash point >75 °C Evaporation rate Not determined Flammability (solid, gas) not relevant, (fluid) Vapor pressure 240 hPa at 20 °C Density not determined Vapor density this information is not available Relative density 1 (water = 1) Solubility(ies) - Water solubility miscible in any proportion Partition coefficient - n-octanol/water (log KOW) this information is not available Auto-ignition temperature 465 °C (auto-ignition temperature (liquids and gases)) Viscosity not determined Explosive properties none Oxidizing properties none
10.1 Reactivity Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture contains reactive substance(s). Risk of ignition. If heated: Risk of ignition 10.2 Chemical stability See below "Conditions to avoid". 10.3 Possibility of hazardous reactions No known hazardous reactions. 10.4 Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Hints to prevent fire or explosion Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary meas-ures against static discharge. 10.5 Incompatible materials Oxidizers 10.6 Hazardous decomposition products Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.
11.1 Information on toxicological effects Test data are not available for the complete mixture. Classification procedure The method for classification of the mixture is based on ingredients of the mixture (additivity formula). Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) Acute toxicity Shall not be classified as acutely toxic. Acute toxicity estimate (ATE) of components of the mixture Name of substance CAS No Exposure route ATE Potassium phosphate monobasic 7778-77-0 inhalation: dust/mist 0.83 mg /l/4h Skin corrosion/irritation Shall not be classified as corrosive/irritant to skin. Serious eye damage/eye irritation Shall not be classified as seriously damaging to the eye or eye irritant. Respiratory or skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity Shall not be classified as germ cell mutagenic. Carcinogenicity Shall not be classified as carcinogenic. Reproductive toxicity Shall not be classified as a reproductive toxicant. Specific target organ toxicity - single exposure Shall not be classified as a specific target organ toxicant (single exposure). Specific target organ toxicity - repeated exposure Shall not be classified as a specific target organ toxicant (repeated exposure). Aspiration hazard Shall not be classified as presenting an aspiration hazard.
12.1 Toxicity Shall not be classified as hazardous to the aquatic environment. 12.2 Persistence and degradability Data are not available. 12.3 Bioaccumulative potential Data are not available. 12.4 Mobility in soil Data are not available. 12.5 Results of PBT and vPvB assessment Data are not available. 12.6 Endocrine disrupting properties Information on this property is not available. 12.7 Other adverse effects Data are not available.
13.1 Waste treatment methods please consider the relevant national or regional provisions
14.1 UN number not subject to transport regulations 14.2 UN proper shipping name 14.3 Transport hazard class(es) not assigned 14.4 Packing group not assigned 14.5 Environmental hazards non-environmentally hazardous acc. to the danger-ous goods regulations 14.6 Other relevant information Shipping container markings and labels for this product, as received, may vary from the contents of sec-tion 14 of the SDS for one or both of the following reasons: •CHEMetrics has packaged this product as Dangerous Goods in Excepted Quantities according to IATA, US DOT, and IMDG regulations. •CHEMetrics has packaged this product as part of a test kit or reagent set composed of various chemic-al reagents and elected to ship as UN 3316 Chemical Kit, Hazard Class 9, Packing Group II or III. In case of reshipment, it is the responsibility of the shipper to determine appropriate labels and mark-ings in accordance with applicable transportation regulations. 14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code The cargo is not intended to be carried in bulk. Information for each of the UN Model Regulations Transport of dangerous goods by road or rail (49 CFR US DOT) - Additional information Not subject to transport regulations. International Maritime Dangerous Goods Code (IMDG) - Additional information Not subject to IMDG. International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information Not subject to ICAO-IATA.
15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States) Toxic Substance Control Act (TSCA) all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III ) - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304) none of the ingredients are listed - Specific Toxic Chemical Listings (EPCRA Section 313) none of the ingredients are listed Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4) Name of substance CAS No Remarks Statutory code Final RQ pounds (Kg) sodium hydroxide 1310-73-2 11000 (454) acetone 67-64-1 45000 (2270) Legend 1"1" indicates that the statutory source is section 311(b)(2) of the Clean Water Act Legend 4"4" indicates that the source is section 3001 of the Resource Conservation and Recovery Act (RCRA) Clean Air Act none of the ingredients are listed Right to Know Hazardous Substance List - Hazardous Substance List (NJ-RTK) Name of substance CAS No Remarks Classifications sodium hydroxide 1310-73-2 CO R1 acetone 67-64-1 F3 Legend CO Corrosive F3 Flammable - Third Degree R1 Reactive - First Degree California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987 none of the ingredients are listed Industry or sector specific available guidance(s) NPCA-HMIS® III Hazardous Materials Identification System. American Coatings Association. Category Rating Description Chronic / none Health 2 temporary or minor injury may occur Flammability 2 material that must be moderately heated or exposed to relatively high ambient temper-atures before ignition can occur Physical hazard 0 material that is normally stable, even under fire conditions, and will not react with water, polymerize, decompose, condense, or self-react. Non-explosive Personal protection - NFPA® 704 National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Re-sponse (United States). Category Degree of hazard Description Flammability 2 material that must be moderately heated or exposed to relatively high ambient temper-atures before ignition can occur Health 2 material that, under emergency conditions, can cause temporary incapacitation or resid-ual injury Instability 0 material that is normally stable, even under fire conditions Special hazard National inventories Country Inventory Status AU AICS not all ingredients are listed CA DSL all ingredients are listed CN IECSC all ingredients are listed EU ECSI all ingredients are listed EU REACH Reg. not all ingredients are listed JP CSCL-ENCS not all ingredients are listed KR KECI not all ingredients are listed MX INSQ not all ingredients are listed NZ NZIoC all ingredients are listed PH PICCS all ingredients are listed TR CICR not all ingredients are listed TW TCSI all ingredients are listed US TSCA all ingredients are listed Legend AICS Australian Inventory of Chemical Substances CICR Chemical Inventory and Control Regulation CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS) DSL Domestic Substances List (DSL) ECSI EC Substance Inventory (EINECS, ELINCS, NLP) IECSC Inventory of Existing Chemical Substances Produced or Imported in China INSQ National Inventory of Chemical Substances KECI Korea Existing Chemicals Inventory NZIoC New Zealand Inventory of Chemicals PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS) REACH Reg. REACH registered substances TCSI Taiwan Chemical Substance Inventory TSCA Toxic Substance Control Act 15.2 Chemical Safety Assessment Chemical safety assessments for substances in this mixture were not carried out.
Key literature references and sources for data OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200. Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA). Classification procedure Physical and chemical properties: The classification is based on tested mixture. Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mix-ture (additivity formula). List of relevant phrases (code and full text as stated in chapter 2 and 3) Code Text H225 Highly flammable liquid and vapor. H227 Combustible liquid. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. Disclaimer This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product. SECTION 1: Identification 1.1 Product identifier Trade name A-1600, A-2500, A-5501, A-7400, A-7900 Other means of identification Activator Solution for Bromine, Chlorine, Hydrogen Peroxide, Ozone, Peracetic Acid Test Kits 1.2 Relevant identified uses of the substance or mixture and uses advised against Component of water analysis test kits: I-2001, I-2019, I-2020, K-1605, K-2500, K-2504, K-2504A, K-2504B, K-2504C, K-2504D, K-2505, K-2511, K-2513, K-5502, K-7404, K-7423, K-7904, K-7904A, K-7904B, K-7904C, K-7904D, K-7913 1.3 Details of the supplier of the safety data sheet CHEMetrics, Inc. 4295 Catlett Road Midland VA 22728 United States Telephone: 1-540-788-9026 Telefax: 1-540-788-4856 e-mail: technical@chemetrics.com Website: www.chemetrics.com 1.4 Emergency telephone number Emergency information service ChemTel Inc.: 1-800-255-3924, +01-813-248-0585 SECTION 2: Hazard(s) identification 2.1 Classification of the substance or mixture Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) Section Hazard class Category Hazard class and cat-egory Hazard state-ment 3.2 skin corrosion/irritation 3Skin Irrit. 3 H316 3.9 specific target organ toxicity - repeated exposure 1STOT RE 1 H372 2.2 Label elements Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word danger - Pictograms GHS08 - Hazard statements H316 Causes mild skin irritation. H372 Causes damage to organs through prolonged or repeated exposure. - Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P314 Get medical advice/attention if you feel unwell. P332+P313 If skin irritation occurs: Get medical advice/attention. P501 Dispose of contents/container to industrial combustion plant. SECTION 3: Composition/information on ingredients 3.1 Substances Not relevant (mixture) 3.2 Mixtures Description of the mixture Name of substance Identifier Wt% Classification acc. to GHS Pictograms water CAS No 7732-18-5 ≥ 88 Potassium iodide CAS No 7681-11-0 11 STOT RE 1 / H372 sodium hydroxide CAS No 1310-73-2 ≤ 0.1 Skin Corr. 1A / H314 Eye Dam. 1 / H318 SECTION 4: First-aid measures 4.1 Description of first-aid measures General notes Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth. Following inhalation If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air. Following skin contact Wash with plenty of soap and water. Following eye contact Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Following ingestion Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed Symptoms and effects are not known to date. SECTION 5: Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2) Unsuitable extinguishing media Water jet 5.2 Special hazards arising from the substance or mixture Hazardous combustion products Carbon monoxide (CO), Carbon dioxide (CO2) 5.3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Remove persons to safety. For emergency responders Wear breathing apparatus if exposed to vapors/dust/aerosols/gases. 6.2 Environmental precautions Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. 6.3 Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains Advice on how to clean up a spill Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder Appropriate containment techniques Use of adsorbent materials. Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. 6.4 Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Recommendations Wear Impact- and splash-resistant eyewear. - Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Use only in well-ventilated areas. Advice on general occupational hygiene Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equip-ment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in con-tainers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs. 7.2 Conditions for safe storage, including any incompatibilities 7.3 Other information For optimum analytical performance, store in the dark and at room temperature. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limit values (Workplace Exposure Limits) Coun-try Name of agent CAS No Identi-fier TWA [ppm] TWA [mg/m³] STEL [ppm] STEL [mg/m³] Ceiling-C [ppm] Ceiling-C [mg/m³] Nota-tion Source US sodium hydroxide 1310-73-2 REL 2 NIOSH REL US sodium hydroxide 1310-73-2 TLV® 2 ACGIH® 2019 US sodium hydroxide 1310-73-2 PEL 2 29 CFR 1910.100 0US sodium hydroxide (caustic soda) 1310-73-2 PEL (CA) 2 Cal/ OSHA PEL Notation Ceiling-C ceiling value is a limit value above which exposure should not occur STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period (unless otherwise specified) TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted average (unless otherwise specified Relevant DNELs of components of the mixture Name of substance CAS No Endpoint Threshold level Protection goal, route of exposure Used in Exposure time Potassium iodide 7681-11-0 DNEL 0.07 mg/m³ human, inhalatory worker (industry) chronic - systemic ef-fects Potassium iodide 7681-11-0 DNEL 1 mg/kg bw/ day human, dermal worker (industry) chronic - systemic ef-fects sodium hydroxide 1310-73-2 DNEL 1 mg/m³ human, inhalatory worker (industry) chronic - local effects Relevant PNECs of components of the mixture Name of substance CAS No Endpoint Threshold level Organism Environmental compartment Exposure time Potassium iodide 7681-11-0 PNEC 0.007 mg /l aquatic organisms freshwater short-term (single in-stance) Potassium iodide 7681-11-0 PNEC 0.007 mg /kg aquatic organisms freshwater sediment short-term (single in-stance) 8.2 Exposure controls Appropriate engineering controls General ventilation. Individual protection measures (personal protective equipment) Eye/face protection Wear eye/face protection. Skin protection - Hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tight-ness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before
Bookmark
Daniel Féau processes personal data in order to optimise communication with our sales leads, our future clients and our established clients.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.