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1.1 Product identifier
Trade name: KEIM SOLDALIT-ME
Nanoform: This product contains nanoforms. 1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the mixture Sol-silicate paint with photocatalytic effect. Uses advised against All other uses are not recommended. 1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
KEIMFARBEN GMBH Keimstraße 16 / 86420 Diedorf Tel. +49 (0)821 4802-0 Fax +49 (0)821 4802-210 www.keim.com / info@keimfarben.de Further information obtainable from:
Product safety department Telefon: 49(0)821/4802-138 E-Mail: sdb.info@keimfarben.de 1.4 Emergency telephone number:
GBK GmbH Global Regulatory Compliance Emergency number: +49(0)6132/84463
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The product is not classified, according to the CLP regulation. 2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 Void Hazard pictograms Void Signal word Void Hazard statements Void 2.3 Other hazards Alkaline product. Avoid contact with skin and eyes. Results of PBT and vPvB assessment
PBT: Not applicable vPvB: Not applicable
3.2 Mixtures
Description:
Aqueous solution of silicic acid potassium salt, silica sol, acrylic polymer, mineral fillers, pigments, additives.
Dangerous components:
CAS: 1312-76-1 EINECS: 215-199-1 Reg.nr.: 01-2119456888-17-xxxx Silicic acid, potassium salt
Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335 Specific concentration limits: Skin Irrit. 2; H315: C ≥40 % Eye Irrit. 2; H319: C ≥ 40 % STOT SE 3; H335: C ≥ 40 % 0.1-≤2.5% CAS: 13463-67-7 EINECS: 236-675-5 Index number: 022-006-00-2 Reg.nr.: 01-2119489379-17-XXXX titanium dioxide [in powder form containing 1 % or more of particles with aerodynamic diameter ≤ 10 μm] Nanoform: Number-based particle size distribution - d10: ≥2 - ≤70 - d50: ≥3 - ≤ 99 - d90: ≥4 - ≤200 Shape: Spheroidal Structure: crystalline forms Crystallinity: crystalline nanoform Surface-to-mass ratio: ≥10 - ≤ 700 0.1-≤2.5% Additional information:
Route of exposure: Inhalation/contraction not given. Alveolar particles (diameter ≤ 10 μm) bound in the paint matrix. For the wording of the listed hazard phrases refer to section 16.
4.1 Description of first aid measures
General information:
No special measures required. When seeing the doctor we suggest to present this safety data sheet. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact:
Immediately wash with water and soap and rinse thoroughly. Do not use solvents or thinners. If skin irritation continues, consult a doctor. After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing:
Rinse mouth and throat well with water. Do not induce vomiting; call for medical help immediately. 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5.1 Extinguishing media
Suitable extinguishing agents:
Product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings. 5.2 Special hazards arising from the substance or mixture
No further relevant information available. 5.3 Advice for firefighters
Special protective equipment: Wear self-contained respiratory protective device. Additional information
In case of fire do not breathe smoke, fumes and vapours. Cool endangered receptacles with water spray. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes. Ensure adequate ventilation Particular danger of slipping on leaked/spilled product. Respect the protection rules (see section 7 and 8). 6.2 Environmental precautions:
Do not allow product to reach soil, sewage system or any water course. Follow local governmental rules and regulations. 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the material collected according to regulations. Clear contaminated areas thoroughly. Flush rests with sufficient amount of water. 6.4 Reference to other sections
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
7.1 Precautions for safe handling
Keep receptacles tightly sealed. Avoid contact with skin and eyes. Do not inhale aerosols. See item 8 (8.2) for information about suitable protective equipment and technical precautions. Respect the protection rules. Information about fire - and explosion protection:
The product is not flammable. No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Keep in the original containers in a cool and dry place. Store only in unopened original receptacles. Information about storage in one common storage facility: Not required. Further information about storage conditions:
Store in a cool place. Protect from frost. Protect from heat and direct sunlight. Storage class: 12 GISCode BSW40 Beschichtungsstoffe, wasserbasiert, alkalisch 7.3 Specific end use(s) No further relevant information available.
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. DNELs 13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles with aerodynamic diameter ≤ 10 μm]
Inhalative Long-term - systemic effects 0.8 mg/m³ (worker)
1312-76-1 Silicic acid, potassium salt
Oral Long-term - systemic effects 0.74 mg/kg bw/day (consumer) Dermal Long-term - systemic effects 0.74 mg/kg bw/day (consumer) 1.49 mg/kg bw/day (worker) Inhalative Long-term - systemic effects 1.38 mg/m³ (consumer) 5.61 mg/m³ (worker) PNECs 1312-76-1 Silicic acid, potassium salt
Aquatic compartment - freshwater 7.5 mg/l (Freshwater) Aquatic compartment - marine water 1 mg/l (Seawater) Aquatic compartment - water, intermittent releases 7.5 mg/l (Freshwater) Sewage treatment plant 348 mg/l (Sewage treatment plant) Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls
Individual protection measures, such as personal protective equipment
General protective and hygienic measures:
Avoid contact with the eyes and skin. Do not inhale aerosols.
Wash hands before breaks and at the end of work. Immediately remove all soiled and contaminated clothing. Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed. Filter: P2 Hand protection Protective gloves Material of gloves
suitable material e.g.: Nitrile impregnated cotton-gloves Recommended thickness of the material: ≥ 0.5 mm Nitrile rubber, NBR Recommended thickness of the material: ≥ 0.4 mm Butyl rubber, BR Recommended thickness of the material: ≥ 0.7 mm The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material
Value for the permeation: level ≥ 6 (480 min) The determined penetration times according to EN 16523-1:2015 are not performed under practical conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye/face protection Tightly sealed goggles Body protection:
Protective work clothing After contact with skin wash thoroughly with water and apply lotion. Environmental exposure controls
See Section 12 and 6.2 No further relevant information available.
9.1 Information on basic physical and chemical properties
General Information
Physical state Liquid Colour: Different, according to colouring. Odour: Odourless Odour threshold: Not determined Melting point/freezing point: Not determined Boiling point or initial boiling point and boiling range >100 °C Flammability Not applicable
Lower and upper explosion limit
Lower: Not applicable Upper: Not applicable Flash point: Not applicable Auto-ignition temperature: Not determined Decomposition temperature: Not determined pH at 20 °C ~11* Viscosity:
Kinematic viscosity Not determined Dynamic at 20 °C: 2.000-2.800* mPas Solubility
water: Fully miscible Partition coefficient n-octanol/water (log value) Not applicable Vapour pressure at 20 °C: ~23 hPa Density and/or relative density
Density at 20 °C: 1.4-1.6* g/cm³ Relative density Not determined Vapour density Not applicable Particle characteristics See section 3. 9.2 Other information *The values are for freshly produced material and may change with the time. Appearance:
Form: Fluid Important information on protection of health and environment, and on safety.
Ignition temperature: Product is not selfigniting. Explosive properties: Product does not present an explosion hazard. Change in condition
Softening point/range
Oxidising properties: Not applicable Evaporation rate Not applicable Information with regard to physical hazard classes
Explosives Void Flammable gases Void Aerosols Void Oxidising gases Void Gases under pressure Void Flammable liquids Void Flammable solids Void Self-reactive substances and mixtures Void Pyrophoric liquids Void Pyrophoric solids Void
Self-heating substances and mixtures Void Substances and mixtures, which emit flammable gases in contact with water Void Oxidising liquids Void Oxidising solids Void Organic peroxides Void Corrosive to metals Void Desensitised explosives Void Other safety characteristics
Photocatalytic properties The product has photocatalytic properties.
10.1 Reactivity No further relevant information available. 10.2 Chemical stability Stable under normal conditions of storage and use. Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions No dangerous reactions known. 10.4 Conditions to avoid No further relevant information available. 10.5 Incompatible materials: Acids 10.6 Hazardous decomposition products:
In case of fire, the following can be released: Silicon dioxid (SiO2) Carbon oxides (COx) No hazardous decomposition products if stored and handled as prescribed.
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity Based on available data, the classification criteria are not met. LD/LC50 values relevant for classification: 13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles with aerodynamic diameter ≤ 10 μm]
Oral LD50 >5,000 mg/kg (rat) Inhalative LC50/4 h >6.82 mg/l (rat) Primary irritant effect:
Skin corrosion/irritation Frequent persistent contact with the skin may cause skin irritation. Serious eye damage/irritation In case of longer exposure, irritating effect is possible. during inhalation: Irritant effect possible. during swallowing: Irritant effect possible. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. Other information (about experimental toxicology):
Experimental analysis are not available. The product was not tested. The statements on toxicology have been derived from the properties of the individual components. Subacute to chronic toxicity:
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Not applicable 11.2 Information on other hazards
Endocrine disrupting properties
None of the ingredients is listed.
12.1 Toxicity
Aquatic toxicity: 13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles with aerodynamic diameter ≤ 10 μm]
ErC50/72h >100 mg/l (algae) LC 50/96 h >1,000 mg/l (Pimephales promelas) 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. 12.5 Results of PBT and vPvB assessment
PBT: Not applicable vPvB: Not applicable 12.6 Endocrine disrupting properties
The product does not contain substances with endocrine disrupting properties. 12.7 Other adverse effects
Additional ecological information:
AOX-indication:
Due to the substance of content which do not include organic jointed halogens, the product can not take influence on the AOX-load of the waste water. According to the formulation contains the following heavy metals and compounds from the EU guideline NO. 2006/11/EC:
The product contains TiO2, BaSO4, ZnS. General notes:
At present there are no ecotoxicological assessments. The statements on ecotoxicology have been derived from the properties of the individual components. Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
13.1 Waste treatment methods
Recommendation
Must not be disposed with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations. European waste catalogue
08 01 12 waste paint and varnish other than those mentioned in 08 01 11 Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations. Recommended cleansing agents: Water, if necessary with cleansing agents.
14.1 UN number or ID number
ADR, IMDG, IATA Void 14.2 UN proper shipping name
ADR, IMDG, IATA Void 14.3 Transport hazard class(es)
ADR, IMDG, IATA
Class Void 14.4 Packing group
ADR, IMDG, IATA Void 14.5 Environmental hazards:
Marine pollutant: No 14.6 Special precautions for user Not applicable 14.7 Maritime transport in bulk according to IMO instruments Not applicable Transport/Additional information: No dangerous good in sense of these transport regulations. UN "Model Regulation": Void
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed. LIST OF SUBSTANCES SUBJECT TO AUTHORISATION (ANNEX XIV)
None of the ingredients is listed. DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronic equipment – Annex II
None of the ingredients is listed. REGULATION (EU) 2019/1148
Annex I - RESTRICTED EXPLOSIVES PRECURSORS (Upper limit value for the purpose of licensing under Article 5(3))
Not relevant ANNEX I EXPORT SUBSTANCES DECLARABLE FOR EXPLOSIVES in quantities > 1%.
None of the ingredients is listed. Annex II - REPORTABLE EXPLOSIVES PRECURSORS
None of the ingredients is listed. Regulation (EC) No 273/2004 on drug precursors
None of the ingredients is listed. Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Community and third countries in drug precursors
None of the ingredients is listed. National regulations:
Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable Product-Code/Giscode: BSW40 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases
H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Department issuing SDS: KEIMFARBEN Germany, Product safety department
Version number of previous version: 13.0 Abbreviations and acronyms:
BOELV: Binding Occupational Exposure Limit Values IOELV : Indicative Occupational Exposure Limit Values OELV: Occupational Exposure Limit Value ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative AGW: Arbeitsplatzgrenzwert (Germany) REACH: Registration, Evaluation and Authorisation of Chemicals (Regulation (EC) No.1907/2006) Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 * Data compared to the previous version altered.
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