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1.1. Product identifier Product name : STARBRIGHT Product code: refer to sales department 1.2. Relevant identified uses of the substance or mixture and uses advised against Neutralizing formulation for Combistar ovens Sectors of use: Industrial Manufacturing[SU3], Manufacture of food products[SU4], Public domain (administration, education, entertainment, services, craftsmen)[SU22] Product category: Washing and Cleaning Products (including solvent based products) Process categories: Use in batch and other process (syn- thesis) where opportunity for exposure arises[PROC4], Transfer of substance or mixture (charging and discharging) at nondedicated facilities[PROC8A], Transfer of substance or mixture (charging and discharging) at dedicated facilities[PROC8B] Not recommended uses Do not use for purposes other than those listed 1.3. Details of the supplier of the safety data sheet Distributore esclusivo/Exclusive supplier: ANGELO PO Grandi Cucine 41012 Carpi (Italy) S/S Romana Sud, 90 Tel. +39.059.639411 - Fax +39.059.642499 e-mail: angelopo@angelopo.it http: www.angelopo.it 1.4. Emergency telephone number Centralino/Switchboard +39.030.2307.1 - (h 8.30-12.00 13.30-18.00 GMT+1; Lingua/Language: Italiano, English)
2.1. Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008: Pictograms: None Hazard Class and Category Code(s): Non hazardous Hazard statement Code(s): Non hazardous 2.2. Label elements Labelling according to Regulation (EC) No 1272/2008: Pictogram, Signal Word Code(s): None Hazard statement Code(s): Non hazardous Supplemental Hazard statement Code(s): EUH210 - Safety data sheet available on request. Precautionary statements: None in particular. Contains (Reg.EC 648/2004): < 5% phosphonates Preservatives: Benzisothiazolinone 2.3. Other hazards Based on the available data, no PBT or vPvB substances are present in accordance with Regulation (EC) 1907/2006, annex XIII Do not ingest. Keep out of reach of children.
3.1 Substances Irrilevant 3.2 Mixtures Refer to paragraph 16 for full text of hazard statements Substance Concentration[ w/w] Classification Index CAS EINECS REACh (1-hydroxyethylidene)bisphospho nic acid, sodium salt >= 3 < 5% 701-238-4 01-2119510 382-52-XXX X Acute Tox. 4, H302 ATE oral = 500,0 mg/kg Citric acid >= 1 < 2,5% 5949-29-1 201-069-1 01-2119457 026-42-XXX X Eye Irrit. 2, H319
4.1. Description of first aid measures Inhalation: ventilate the room. Immediately remove the patient from the contaminated area and keep him at rest in a well ventilated area. In case of malaise consult a doctor. Direct contact with the skin (of the pure product): wash with plenty of water and soap. Direct contact with eyes (of the pure product): wash immediately with plenty of water for at least 10 minutes. Ingestion: not dangerous. Do not administer anything if the person is unconscious. In case of discomfort. consult a doctor 4.2. Most important symptoms and effects, both acute and delayed No data available. 4.3. Indication of any immediate medical attention and special treatment needed Symptomatic treatment
5.1. Extinguishing media Recommended extinguishing media: Nebulized water, CO2, foam, chemical powders depending on the materials involved in the fire. Extinguishing media to avoid: Water jets. Use water jets only to cool the surfaces of containers exposed to fire 5.2. Special hazards arising from the substance or mixture No data available. 5.3. Advice for firefighters Use respiratory protection. Full safety helmet and protective clothing. The water spray can be used to protect people involved in extinguishing. It is also recommended to use self-contained breathing apparatus, especially if you work in closed and poorly ventilated places. Cool the containers with jets of water
6.1. Personal precautions, protective equipment and emergency procedures 6.1.1 For non-emergency personnel: Move away from the area surrounding the spill or release. Not smoking. Wear gloves and protective clothing. 6.1.2 For emergency responders: Eliminate all open flames and possible sources of ignition. Not smoking. Provide adequate ventilation. Evacuate the danger area and, if necessary, consult an expert. 6.2. Environmental precautions Contain spills with earth or sand. If the product has entered a watercourse, sewers or has contaminated soil or vegetation, notify the authorities. Dispose of the waste material in compliance with the regulations 6.3. Methods and material for containment and cleaning up 6.3.1 Containment: Recover the product for reuse, if possible, or for removal. Possibly absorb it with inert materia or sucked it. Prevent it from entering the sewer system. 6.3.2 Cleaning up: After wiping up, wash with water the area and materials involved 6.3.3 Other information: None in particular. 6.4. Reference to other sections Refer to paragraphs 8 and 13 for more information
7.1. Precautions for safe handling Avoid contact and inhalation of vapors At work do not eat or drink. See also paragraph 8 below. 7.2. Conditions for safe storage, including any incompatibilities Keep in original container closed tightly. Do not store in open or unlabelled containers. Keep containers upright and safe by avoiding the possibility of falls or collisions. Store in a cool and dry place, away from heat sources and direct exposure to sunlight. 7.3. Specific end use(s) Industrial Manufacturing: Handle with care. Store in a well ventilated place and away from heat sources, in the original container, well closed Manufacture of food products: Handle with care. Store in a clean, dry, ventilated area away from heat and direct sunlight. Keep container tightly closed. Public domain (administration, education, entertainment, services, craftsmen): Handle with care. Store in a well ventilated place and away from heat sources, in the original container, well closed
8.1. Control parameters - Substance: (1-hydroxyethylidene)bisphosphonic acid, sodium salt DNEL Systemic effects Long term Workers inhalation = 2,95 (mg/m3) Systemic effects Long term Workers dermal = 17 (mg/kg bw/day) PNEC Sweet water = 0,068 (mg/l) sediment Sweet water = 136 (mg/kg/sediment) Sea water = 0,007 (mg/l) - Substance: Citric acid PNEC Sweet water = 0,44 (mg/l) sediment Sweet water = 34,6 (mg/kg/sediment) Sea water = 0,044 (mg/l) sediment Sea water = 3,46 (mg/kg/sediment) STP = 1000 (mg/l) ground = 33,1 (mg/kg ground) 8.2. Exposure controls Appropriate engineering controls: Industrial Manufacturing: No specific monitoring foreseen (act according to good practice and specific rules for the type of risk associated) Manufacture of food products: No specific monitoring foreseen (act according to good practice and specific rules for the type of risk associated) Public domain (administration, education, entertainment, services, craftsmen): No specific monitoring foreseen (act according to good practice and specific rules for the type of risk associated) 8.2.2 Individual protection measures: (a) Eye / face protection Not needed for normal use. In case of possible splashes, use safety goggles (EN 166) (b) Skin protection (i) Hand protection Not needed for normal use. In the case of sensitive subjects or by prolonged contact of the pure product, use chemical-resistant protective gloves (EN 374-1/EN374-2/EN374-3) unless otherwise provided by the employer (ii) Other During working operation wear protective clothing (generic workwear / antacid, safety shoes or other protective equipment) according to the instructions of the employer (c) Respiratory protection Not needed for normal use. During manual operations in case of insufficient ventilation, use adequate protection mask (UNI EN 405) unless otherwise provided by the employer and/or environmental hygiene investigations (d) Thermal hazards No hazard to report Environmental exposure controls: Use according to good working practices and avoid to disperse the product into the environment.
9.1. Information on basic physical and chemical properties Value Determination method Physical and chemical properties Physical state Liquid Colour light blue Odour not determined as considered not relevant for the characterization of the product Value Determination method Physical and chemical properties Odour threshold not determined as considered not relevant for the characterization of the product Melting point/freezing point not determined as considered not relevant for the characterization of the product Boiling point or initial boiling point and boiling range not determined as it is considered not relevant for the characterization of the product Flammability not determined as it is considered not relevant for the characterization of the product Lower and upper explosion limit not determined as it is considered not relevant for the characterization of the product Flash point not determined as it is considered not relevant for the characterization of the product Auto-ignition temperature not determined as it is considered not relevant for the characterization of the product Decomposition temperature not determined as it is considered not relevant for the characterization of the product pH 5,0 ± 0,5 (20°C) Kinematic viscosity not determined as it is considered not relevant for the characterization of the product Solubility in water Water solubility miscible in all proportions Partition coefficient n-octanol/water (log value) not determined as it is considered not relevant for the characterization of the product Vapour pressure not determined as it is considered not relevant for the characterization of the product Density and/or relative density 1,06 ± 0,05 (20°C) Relative vapour density not determined as it is considered not relevant for the characterization of the product Particle characteristics not determined as considered not relevant for the characterization of the product 9.2. Other information 9.2.1 Information with regard to physical hazard classes No data available. 9.2.2 Other safety characteristics No data available.
10.1. Reactivity Related to contained substances: Citric acid: It is not pyrophoric 10.2. Chemical stability Stable at room temperature and under normal conditions of use 10.3. Possibility of hazardous reactions There are no hazardous reactions 10.4. Conditions to avoid Keep away from heat sources. If possible, avoid direct incidence of solar radiation. 10.5. Incompatible materials It can generate flammable gases in contact with elementary metals, nitrides, inorganic sulfide, strong reducing agents. It can generate toxic gases in contact with inorganic solfide, strong reducing agents. 10.6. Hazardous decomposition products Does not decompose when used for intended uses.
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 ATE(mix) oral = 12.500,0 mg/kg (a) acute toxicity: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Ingestion-rat LD50 (mg/kg/bw 24h): 300-2000 Skin contact-LC50 rat/coniglio (mg/kg/bw 24h): > 5000 Inhalation-rat LD50 (mg/l/4h): n.a. Citric acid: Not classified (b) skincorrosion/irritation: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-corrosive Citric acid: Not corrosive (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-irritating Citric acid: Not irritating (c) serious eye damage/irritation: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-corrosive Citric acid: Not corrosive (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-irritating Citric acid: Irritating (d) respiratoryorskinsensitisation: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-sensitizing Citric acid: Not available (e) germ cell mutagenicity: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-mutagenic Citric acid: Not mutagenic (f) carcinogenicity: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-carcinogenic Citric acid: Not carcinogenic (g) eproductivetoxicity: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Non-toxic for reproduction Citric acid: Non-toxic for reproduction (h) specific target organ toxicity (STOT) single exposure: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Not available Citric acid: Not available (i) specific target organ toxicity (STOT) repeated exposure(1-hydroxyethylidene)bisphosphonic acid, sodium salt: Not available Citric acid: Rat: NOAEL: 4,000 mg / kg LOAEL: 8,000 mg / kg Application method: Oral Exposure time: 10 d Doses: 2, 4, 8, 16 g / kg bw / day (j) aspiration hazard: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Not disponìbile Citric acid: Unavailable Related to contained substances: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: LD50 (rat) Oral (mg/kg body weight) = 500 11.2. Information on other hazards No data available.
12.1. Toxicity Related to contained substances: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Acute toxicity-fish LC50 (mg/l/96h): 2670-3400 Acute toxicity-crustacea EC50 (mg/l/48 h): 466-610 Acute algae toxicity ErC50 (mg/l/72-96h): > 960 Chronic toxicity-crustaceans NOEC (mg/l): 0.1 C(E)L50 (mg/l) = 466 NOEC (mg/l) = 0,1 Citric acid: Acute toxicity - fish LC50 (mg / l / 96h): 440 Acute toxicity - crustaceans EC50 (mg / l / 48h): 1535 Acute toxicity algae ErC50 (mg / l / 72-96h): 425 C(E)L50 (mg/l) = 1535 Use according to good working practices and avoid to disperse the product into the environment. 12.2. Persistence and degradability Related to contained substances: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: ~ 50% OECD 302 B * COD (Std. Method 5220 D): 330 mg / g * BOD-5 (Std. Method 5210 B): 20 mg / g * MBAS: 0 mg / g * BiAS: 0 mg / g Citric acid: Easily biodegradable 12.3. Bioaccumulative potential Related to contained substances: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: No other information available Citric acid: Not bioaccumulative 12.4. Mobility in soil Related to contained substances: (1-hydroxyethylidene)bisphosphonic acid, sodium salt: Not available Citric acid: Unavailable 12.5. Results of PBT and vPvB assessment Based on the available data, no PBT or vPvB substances are present in accordance with Regulation (EC) 1907/2006, annex XIII 12.6. Endocrine disrupting properties No data available. 12.7. Other adverse effects No adverse effects Regulation (EC) No 2006/907 - 2004/648 The (I) surfactant (s) content (s) in this preparation complies (comply) with (i) the biodegradability criteria as laid down in Regulation CE/648/2004 on detergents. All data are held at the disposal of the competent authorities of Member States and will be provided, at their direct request or at the request of a detergent manufacturer, to those authorities.
13.1. Waste treatment methods Do not reuse empty containers. Dispose of them in accordance with the regulations in force. Any remaining product should be disposed of according to applicable regulations by addressing to authorized companies. Recover if possible. Operate according to local or national regulations
14.1. UN number or ID number Not included in the field of application of regulations concerning the transport of dangerous goods: by road (ADR); by rail (RID); by air (ICAO / IATA); by sea (IMDG). 14.2. UN proper shipping name None 14.3. Transport hazard class(es) None 14.4. Packing group None 14.5. Environmental hazards None 14.6. Special precautions for user No data available. 14.7. Maritime transport in bulk according to IMO instruments Transport in bulk is not foreseen
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Restrictions relating to the product or contained substances (All. XVII Reg. EC 1907/2006): not applicable Substances in Candidate List (art. 59 Reg. EC 1907/2006): the product does not contain SVHC in a proportion ≥ 0.1%. Substances subject to authorisation (Ann. XIV Reg. CEC 1907/2006): the product does not contain SVHC in a proportion ≥ 0.1%. Reg. EC 648/04: see 2.2 Reg. (EU) n. 1169/2011: see 2.2 Reg (UE) 528/2012: see.to 2.2 Regulation (EU) 1332/2008; see p.2.2 15.2. Chemical safety assessment No chemical safety assessment was carried out by the supplier
16.1. Other information Points modified compared to previous release: 7.1. Precautions for safe handling, 7.3. Specific end use(s), 8.1. Control parameters, 8.2. Exposure controls, 10.1. Reactivity, 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008, 12.1. Toxicity, 12.2. Persistence and degradability, 12.3. Bioaccumulative potential, 12.4. Mobility in soil, 12.5. Results of PBT and vPvB assessment, 12.6. Endocrine disrupting properties, 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture, 15.2. Chemical safety assessment Description of hazard statements set out in paragraph 3 H302 = Harmful if swallowed. H319 = Causes serious eye irritation. Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: No hazard to report. Classification procedure: Calculation method Main normative references: Reg. (CE) n. 1907 del 18/12/06 REACH (Registration, Evaluation and Authorisation of CHemicals) et seq. Reg. (CE) 1272/2008 CLP (Classification Labelling and Packaging) et seq. Regulation (EC) n. 648 of 31/03/04 (on detergents) et seq. Regulation (UE) n. 1169/2011 (on the provision of food information to consumers) Directive 2012/18/EU (on the control of major-accident hazards involving dangerous substances) et seq. Regulation (UE) 528/2012 (Biocides) et seq. Regulation (EU) 1332/2008 (Food enzymes) Training required: This document must be submitted to the employer to determine the possible need for appropriate training for workers to ensure protection of human health and the environment. n.a.: not applicable n.d.: not available ADR: Accord europèen relative au transport International des merchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) ATE: Acute Toxicity Estimat BFC: BioconCentration Factor BOD: Biochemical Oxigen Demand CAS: Chemical Abstract Service number CAP: Centre AntiPoison CE/EC number EINECS (European Inventory of existing Commercial Substances) e ELINCS (European List of notified Chemical Substances) CL50/LC50: Lethal Concentration 50 DL50/LD50: Lethal Dose 50 COD: Chemical Oxygen Demand DNEL: Derived No Effect Level EC50: half maximal Effective Concentration ERC: Enviroment Release Classes EU/UE: European Union IATA: International Air Transport Association ICAO: International Civil Aviation Organization IMDG: International Maritime Dangerous Goods code Kow: Octanol water partition coefficient NOEC: No Observed Effect Concentration OEL: Occupational Exposure Limit PBT: Persistent Bioaccumulative and Toxic PC: Product Categories PNEC: Predicted No Effect Concentration PROC: Process Categories RID: Règlement concernent le transport International ferroviaire des merchandises dangereuses (Regulations concerning International rail transport of dangerous goods) STOT: Target Organ Systemic Toxicity STOT (RE): Repeated Exposure STOT (SE): Single Exposure STP: Sewage Treatment Plants SU: Sector of Use SVCH: Substance of Very High Concern TLV: Threshold Limit Value vPvB: Very Persistent Very Bioaccumulative References and Sources: • ECHA Registered Substances: • https://echa.europa.eu/web/guest/information-on-chemicals/registered-substances • SDS supplier • GESTIS DNEL Database: http://www.dguv.de/ifa/gestis/gestis-dnel-datenbank/index-2.jsp • GESTIS International Limit Value: http://limitvalue.ifa.dguv.de This msds was made in good faith by technical Office on the basis of the information available at the date of the last revision. The person in charge must regularly inform the employees about the specific risks they encounter when using this substance/product. The information contained here relate only to the substance/the preparation indicated and may not apply if the product is used improperly or in combination with others. Nothing contained herein shall be construed as a guarantee, either express or implied. It is the responsibility of the user to ensure the opportunities and completeness of the information contained herein for their own particular use. *** this tab annuls and replaces any previous edition. (IIXX) Changes to the previous edition: updating to reg.878/2020
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